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In 1, some of the factors which complicate the appearance of infrared spectra were de ned, i.e. overtones and combination bands, coupling, Fermi resonance and vibration rotation bands. Another factor, hydrogen bonding, may also contribute to notable changes in infrared spectra. The presence of this type of bonding in molecules can introduce additional, and sometimes misleading, information into the spectra. It is important to be aware of such factors before tackling the interpretation of a given spectrum. Quantitative infrared spectroscopy can provide certain advantages over other analytical techniques. This approach may be used for the analysis of one component of a mixture, especially when the compounds in the mixture are alike chemically or have very similar physical properties (for example, structural isomers). In these instances, analysis using ultraviolet/visible spectroscopy, for instance, is dif cult because the spectra of the components will be nearly identical. Chromatographic analysis may be of limited use because separation, of say isomers, is dif cult to achieve. The infrared spectra of isomers are usually quite different in the ngerprint region. Another advantage of the infrared technique is that it can be non-destructive and requires a relatively small amount of sample. In this present chapter, an introduction is provided on how infrared spectroscopy can be used for quantitative analysis. First, the various ways in which an infrared spectrum can be manipulated for analysis are outlined. Concentration is an important issue in quantitative analysis and the important relationships are introduced. Not only may quantitative infrared analysis be carried out on simple systems, it can also be applied to multi-component systems. Here, some straightforward examples will be used to demonstrate the analysis of the data obtained, while the calibration methods commonly applied to such infrared data will also be described.

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Several of the portfolio companies appear to have no long-term debt, while others seem to have signi cant long-term debt Another good way of checking on the liquidity of the portfolio is to look into the volume of each holding in the portfolio This allows us to question speci c company holdings and to compile a weighted average volume for the total portfolio to compare against other managers we are reviewing Most investment databases (and Web-based investment sites) offer a number of statistics related to stock volume I tend to focus on average daily stock volume (such as 30-day, 90-day, 12-month) instead of just a single day s worth because the average tends to smooth out the number and helps to quickly eliminate any outliers.

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Overview So far a data set has been grouped according to speci c values for each of the variables. In Figure 6.26, 26 observations (A to Z) are characterized by three

Using the volume information at the stock level, we can calculate how many days it would take to fully liquidate the position using the following formula: # Days to Exit = # of Shares Average Shares Traded.

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Figure 3.13 Infrared spectrum of p-xylene in cyclohexane (2 vol%, 0.1 mm pathlength). From Stuart, B., Modern Infrared Spectroscopy, ACOL Series, Wiley, Chichester, UK, 1996. University of Greenwich, and reproduced by permission of the University of Greenwich.

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nancial land, will shatter VaR), but it would reduce the scope for error, as now the number of exceptions required to deem the tool a failure are much reduced and thus more probable Thus, enhanced certainty is sadly transformed into enhanced unreliability Of course, no coverage of the latest VaR disaster would be even in the vicinity of complete without detailed analysis of the Bear Stearns and Lehman Brothers stories After all, both of them did go down as a result of the crisis We are not talking here about some bothersomely largerthan-usual setback, we are talking about the disappearing of two of the most venerable and traditional nancial powerhouses in the world.

ISO 20022 messages are available for the complete end-to-end payments chain: customer to bank (payment), bank to bank (payment clearing and settlement) and reporting (cash management). A big driver for adoption of ISO 20022 in the payments arena is the Single Euro Payments Area (SEPA), which is currently replacing domestic retail credit transfers and direct debits with standardised European payments that use ISO 20022 messages. Real Time Gross Settlement Systems (RTGS) and low value payments systems around the world have also shown interest in adopting ISO 20022, while others are focusing on building alignment with the standard.

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